Hunting for the magnesium(I) species: formation, structure, and reactivity of some donor-free Grignard compounds.
نویسندگان
چکیده
Magnesium bromide radicals have to be prepared as high-temperature molecules and trapped as a metastable solution because a seemingly simple reduction of donor-free Grignard compounds failed. However, the essential role of magnesium(I) species during the formation of Grignard compounds could be demonstrated experimentally.
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عنوان ژورنال:
- Angewandte Chemie
دوره 51 36 شماره
صفحات -
تاریخ انتشار 2012